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ISSN  2096-3955

CN  10-1502/P

Citation: Qiang Zhang, QingSong Liu, 2018: Changes in diffuse reflectance spectroscopy properties of hematite in sediments from the North Pacific Ocean and implications for eolian dust evolution history, Earth and Planetary Physics, 2, 342-350. doi: 10.26464/epp2018031

2018, 2(4): 342-350. doi: 10.26464/epp2018031


Changes in diffuse reflectance spectroscopy properties of hematite in sediments from the North Pacific Ocean and implications for eolian dust evolution history


University of Chinese Academy of Sciences, Beijing 100049, China


State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China


Department of Ocean Science & Engineering, Southern University of Science and Technology, Shenzhen 518055, China


Laboratory for Marine Geology, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266061, China

Corresponding author: QingSong Liu, qsliu@sustc.edu.cn

Received Date: 2018-06-21
Web Publishing Date: 2018-07-01

Eolian dust preserved in deep-sea sediments of the North Pacific Ocean (NPO) is an important recorder of paleoclimatic and paleoenvironmental changes in the Asian inland. To better understand changes in the dust provenances, in this study diffuse reflectance spectroscopy (DRS) was used to extract the eolian signal recorded in sediments of ODP Hole 885A recovered from the NPO. First, we systematically investigated sieving effects on the DRS data; then band positions of hematite (obtained from the second order derivative curves of the K-M remission function spectrum derived from the DRS) were used to distinguish different provenances of the eolian dust preserved in the pelagic sediments of this hole. Our results show that the sieving (38 μm) process can suppress effectively the experimental errors. Eolian signatures from Chinese Loess Plateau (CLP) sources and non-CLP-sources have been identified in the pelagic sediments of ODP Hole 885A from the late Pliocene to the early Pleistocene. The provenance differences account for the discrepancies in the eolian records recovered from the pelagic sediments in the NPO and profiles in the CLP. Temporal changes in dust provenances are caused by the latitudinal movement of the westerly jet mainstream. The hematite DRS band position is a useful tool to distinguish the provenance of eolian components preserved in pelagic sediments.

Key words: eolian dust, diffuse reflectance spectroscopy, hematite

An, Z. S., Kutzbach, J. E., Prell, W. L., and Porter, S. C. (2001). Evolution of Asian monsoons and phased uplift of the Himalaya-Tibetan plateau since late Miocene times. Nature, 411(6833), 62–66. https://doi.org/10.1038/35075035

Bailey, I., Liu, Q. S., Swann, G. E., Jiang, Z. X., Sun, Y. B., Zhao, X., and Roberts, A. P. (2011). Iron fertilisation and biogeochemical cycles in the sub-Arctic northwest Pacific during the late Pliocene intensification of northern hemisphere glaciation. Earth Planet. Sci. Lett., 307(3–4), 253–265. https://doi.org/10.1016/j.jpgl.2011.05.029

Balsam, W. L., and Deaton, B. C. (1991). Sediment dispersal in the Atlantic Ocean: evaluation by visible light spectra. Rev. Aquat. Sci., 4(4), 411–417.

Balsam, W., Ji, J. F., and Chen, J. (2004). Climatic interpretation of the Luochuan and Lingtai loess sections, China, based on changing iron oxide mineralogy and magnetic susceptibility. Earth Planet. Sci. Lett., 223(3–4), 335–348. https://doi.org/10.1016/j.jpgl.2004.04.023

Balsam, W. L., Otto-Bliesner, B. L., and Deaton, B. C. (1995). Modern and last glacial maximum eolian sedimentation patterns in the Atlantic Ocean interpreted from sediment iron oxide content. Paleoceanography, 10(3), 493–507. https://doi.org/10.1029/95PA00421

Bory, A. J. M., Biscaye, P. E., and Grousset, F. E. (2003). Two distinct seasonal Asian source regions for mineral dust deposited in Greenland (NorthGRIP). Geophys. Res. Lett., 30(4), 1167. https://doi.org/10.1029/2002GL016446.

Deaton, B. C., and Balsam, W. L. (1991). Visible spectroscopy; a rapid method for determining hematite and goethite concentration in geological materials. J. Sedim. Res., 61(4), 628–632. https://doi.org/10.1306/D4267794-2B26-11D7-8648000102C1865D

Ding, Z. L., Derbyshire, E., Yang, S. L., Sun, J. M., and Liu, T. S. (2005). Stepwise expansion of desert environment across northern China in the past 3.5 Ma and implications for monsoon evolution. Earth Planet. Sci. Lett., 237(1-2), 45–55. https://doi.org/10.1016/j.jpgl.2005.06.036

Dong, Z., Shi, X. F., Ge, C. D., Zou, J. J., Yao, Z. Q., Gorbarenko, S., Wang, C. L., and Zong, X. (2017). Evolution of westerly jet during the last 60 ka: evidence from core deposits in the central Japan (East) Sea. Chin. Sci. Bull., 62(11), 1172–1184. https://doi.org/10.1360/N972016-00861

Evans, M. E., and Heller F. (2003). Environmental Magnetism: Principles and Applications of Enviromagnetics. San Diego, Calif: Academic Press.

Guo, Z. T., Ruddiman, W. F., Hao, Q. Z., Wu, H. B., Qiao, Y. S., Zhu, R. X., Peng, S. Z., Wei, J. J., Yuan, B. Y., and Liu, T. S. (2002). Onset of Asian desertification by 22 Myr ago inferred from loess deposits in China. Nature, 416(6877), 159–163. https://doi.org/10.1038/416159a

Hovan, S. A., Rea, D. K., Pisias, N. G., and Shackleton, N. J. (1989). A direct link between the China loess and marine δ18O records: Aeolian flux to the north Pacific. Nature, 340(6231), 296–298. https://doi.org/10.1038/340296a0

Hovan, S. A., Rea, D. K., and Pisias, N. G. (1991). Late Pleistocene continental climate and oceanic variability recorded in northwest pacific sediments. Paleoceanography, 6(3), 349–370. https://doi.org/10.1029/91PA00559

Husar, R. B., Prospero, J. M., and Stowe, L. L. (1997). Characterization of tropospheric aerosols over the oceans with the NOAA advanced very high resolution radiometer optical thickness operational product. J. Geophys. Res.: Atmos., 102(D14), 16889–16909. https://doi.org/10.1029/96JD04009

Ji, J. F., Chen, J., Balsam, W., Lu, H. Y., Sun, Y. B., and Xu, H. F. (2004). High resolution hematite/goethite records from Chinese loess sequences for the last glacial-interglacial cycle: Rapid climatic response of the East Asian Monsoon to the tropical Pacific. Geophys. Res. Lett., 31(3), L03207. https://doi.org/10.1029/2003GL018975

Kyte, F. T., Leinen, M., Heath, G. R., and Zhou, L. (1993). Cenozoic sedimentation history of the central North Pacific: Inferences from the elemental geochemistry of core LL44-GPC3. Geochim. Cosmochim. Acta, 57(8), 1719–1740. https://doi.org/10.1016/0016-7037(93)90109-A

Larrasoaña, J. C., Roberts, A. P., Rohling, E. J., Winklhofer, M., and Wehausen, R. (2003). Three million years of monsoon variability over the northern Sahara. Climate Dyn., 21(7-8), 689–698. https://doi.org/10.1007/s00382-003-0355-z

Li, S. H., Yao, T. D., Tian, L. D., and Wang, P. L. (2011). Seasonal transition characteristics of the westerly jet: Study based on field observations at an altitude of 6900 m on the Mt. Xixiabangma Dasuopu glacier. Chin. Sci. Bull., 56(18), 1912–1920. https://doi.org/10.1007/s11434-011-4508-x

Liu, Q. S., Roberts, A. P., Larrasoaña, J. C., Banerjee, S. K., Guyodo, Y., Tauxe, L., and Oldfield, F. (2012). Environmental magnetism: principles and applications. Rev. Geophys., 50(4), RG4002. https://doi.org/10.1029/2012RG000393

Liu, Q. S., Sun, Y. B., Qiang, X. K., Tada, R., Hu, P. X., Duan, Z. Q., Jiang, Z. X., Liu, J. X., and Su, K. (2015). Characterizing magnetic mineral assemblages of surface sediments from major Asian dust sources and implications for the Chinese loess magnetism. Earth Planet. Space, 67(1), 61. https://doi.org/10.1186/s40623-015-0237-8

Liu, Q. S., Torrent, J., Barrón, V., Duan, Z. Q., and Bloemendal, J. (2011). Quantification of hematite from the visible diffuse reflectance spectrum: effects of aluminium substitution and grain morphology. Clay Miner., 46(1), 137–147. https://doi.org/10.1180/claymin.2011.046.1.137

Liu, D. S. (1985). Loess and the Environment (in Chinese). Beijing: China Ocean Press.

Liu, X. M., Ma, M. M., Wu, H. B., and Zhou, Z. B. (2017). Identification of Aeolian loess deposits on the Indo-Gangetic plain (India) and their significance. Sci. China Earth Sci., 60(3), 428–437. https://doi.org/10.1007/s11430-016-5167-1

McCulloch, M. T., and Wasserburg, G. J. (1978). Sm-Nd and Rb-Sr chronology of continental crust formation. Science, 200(4345), 1003–1011. https://doi.org/10.1126/science.200.4345.1003

Nagashima, K., Suzuki, Y., Irino, T., Nakagawa, T., Tada, R., Hara, Y., Yamada, K., and Kurosaki, Y. (2016). Asian dust transport during the last century recorded in Lake Suigetsu sediments. Geophys. Res. Lett., 43(6), 2835–2842. https://doi.org/10.1002/2015GL067589

Nagashima, K., Tada, R., Matsui, H., Irino, T., Tani, A., and Toyoda, S. (2007). Orbital- and millennial-scale variations in Asian dust transport path to the Japan Sea. Palaeogeogr. Palaeoclimatol. Palaeoecol., 247(1-2), 144–161. https://doi.org/10.1016/j.palaeo.2006.11.027

Nagashima, K., Tada, R., Tani, A., Sun, Y. B., Isozaki, Y., Toyoda, S., and Hasegawa, H. (2011). Millennial-scale oscillations of the westerly jet path during the last glacial period. J. Asian Earth Sci., 40(6), 1214–1220. https://doi.org/10.1016/j.jseaes.2010.08.010

Nakai, S. I., Halliday, A. N., and Rea, D. K. (1993). Provenance of dust in the Pacific Ocean. Earth Planet. Sci. Lett., 119(1-2), 143–157. https://doi.org/10.1016/0012-821X(93)90012-X

Nie, J. S., King, J. W., and Fang, X. M. (2008). Correlation between the magnetic susceptibility record of the Chinese Aeolian sequences and the marine benthic oxygen isotope record. Geochem. Geophys. Geosyst., 9(12). https://doi.org/10.1029/2008GC002243

Nie, J., Pullen, A., Garzione, C. N., Peng, W., & Wang, Z. (2018). Pre-Quaternary decoupling between Asian aridification and high dust accumulation rates. Sci Adv 4 (2), eaao6977. https://doi.org/10.1126/sciadv.aao6977

Nie, J., Stevens, T., Rittner, M., Stockli, D., Garzanti, E., Limonta, M., ... & Lu, H. (2015). Loess plateau storage of northeastern Tibetan plateau-derived Yellow River sediment. Nature Communications, 6, 8511. https://doi.org/10.1038/ncomms9511

Oldfield, F., Chiverrell, R. C., Lyons, R., Williams, E., Shen, Z., Bristow, C., Bloemendal, J., Torrent, J., and Boyle, J. F. (2014). Discriminating dusts and dusts sources using magnetic properties and hematite: Goethite ratios of surface materials and dust from North Africa, the Atlantic and Barbados. Aeolian Res., 13, 91–104. https://doi.org/10.1016/j.aeolia.2014.03.010

Olivarez, A. M., Owen, R. M., and Rea, D. K. (1991). Geochemistry of eolian dust in pacific pelagic sediments: implications for paleoclimatic interpretations. Geochim. Cosmochim. Acta, 55(8), 2147–2158. https://doi.org/10.1016/0016-7037(91)90093-K

Ono, Y., Naruse, T., Ikeya, M., Kohno, H., and Toyoda, S. (1998). Origin and derived courses of eolian dust quartz deposited during marine isotope stage 2 in East Asia, suggested by ESR signal intensity. Global Planet. Change, 18(3-4), 129–135. https://doi.org/10.1016/S0921-8181(98)00012-5

Pettke, T., Halliday, A. N., Hall, C. M., and Rea, D. K. (2000). Dust production and deposition in Asia and the north Pacific Ocean over the past 12 Myr. Earth Planet. Sci. Lett., 178(3-4), 397–413. https://doi.org/10.1016/S0012-821X(00)00083-2

Prospero, J. M., Ginoux, P., Torres, O., Nicholson, S. E., and Gill, T. E. (2002). Environmental characterization of global sources of atmospheric soil dust identified with the nimbus 7 total ozone mapping spectrometer (TOMS) absorbing aerosol product. Rev. Geophys., 40(1). https://doi.org/10.1029/2000RG000095

Rea, D. K. (1994). The paleoclimatic record provided by eolian deposition in the deep sea: The geologic history of wind. Rev. Geophys., 32(2), 159–195. https://doi.org/10.1029/93RG03257

Rea, D. K., Basov, I. A., Janecek, T. R., Palmer-Julson, A., et al. (1993). Sites 885/886. In: Proceedings of the Ocean Drilling Program: Initial Reports (Vol. 145, pp. 303–334). College Station, TX: Ocean Drilling Program. https://doi.org/10.2973/odp.proc.ir.145.1993

Rea, D., Janecek, T., 1981. Mass-accumulation rates of the non-authigenic inorganic crystalline (eolian) component of deep-sea sediments from the western MidPacific Mountains, Deep Sea Drilling Project Site 463. Init. Rep. 62, 653–659

Roberts, A. P., Rohling, E. J., Grant, K. M., Larrasoaña, J. C., and Liu, Q. S. (2011). Atmospheric dust variability from Arabia and China over the last 500,000 years. Quat. Sci. Rev., 30(25-26), 3537–3541. https://doi.org/10.1016/j.quascirev.2011.09.007.

Scheinost, A. C., Chavernas, A., Barrón, V., and Torrent, J. (1998). Use and limitations of second-derivative diffuse reflectance spectroscopy in the visible to near-infrared range to identify and quantify Fe oxide minerals in soils. Clays Clay Miner., 46(5), 528–536. https://doi.org/10.1346/CCMN.1998.0460506

Schiemann, R., Lüthi, D., and Schär, C. (2009). Seasonality and interannual variability of the westerly jet in the Tibetan Plateau region. J. Climate, 22(11), 2940–2957. https://doi.org/10.1175/2008JCLI2625.1

Serno, S., Winckler, G., Anderson, R. F., Hayes, C. T., McGee, D., Machalett, B., Ren, H. J., Straub, S. M., Gersonde, R., and Haug, G. H. (2014). Eolian dust input to the Subarctic North Pacific. Earth Planet. Sci. Lett., 387, 252–263. https://doi.org/10.1016/j.jpgl.2013.11.008

Shen, X. Y., Wan, S. M., France-Lanord, C., Clift, P. D., Tada, R., Révillon, S., Shi, X. F., Zhao, D. B., Liu, Y. G., ... and Li, A. C. (2017). History of Asian eolian input to the Sea of Japan since 15 Ma: Links to Tibetan uplift or global cooling?. Earth Planet. Sci. Lett., 474, 296–308. https://doi.org/10.1016/j.jpgl.2017.06.053

Snoeckx, H., Rea, D. K., Jones, C. E., and Ingram, B. L. (1995). Eaolian and silica deposition in the central North Pacific: results from sites 885/886. In Proceedings of the Ocean Drilling Program, Scientific Results (vol. 145, pp. 219–230). College Station, TX, US: Ocean Drilling Program.

Stancin, A. M., Gleason, J. D., Rea, D. K., Owen, R. M., Moore Jr, T. C., Blum, J. D., and Hovan, S. A. (2006). Radiogenic isotopic mapping of late Cenozoic eolian and hemipelagic sediment distribution in the east-central Pacific. Earth Planet. Sci. Lett., 248(3-4), 840–850. https://doi.org/10.1016/j.jpgl.2006.06.038

Sun, J. M., and Liu, T. S. (2000). Stratigraphic evidence for the uplift of the Tibetan Plateau between ~1.1 and ~0.9 Myr ago. Quat. Res., 54(3), 309–320. https://doi.org/10.1006/qres.2000.2170

Sun, J. M., Zhang, M. Y., and Liu, T. S. (2001). Spatial and temporal characteristics of dust storms in China and its surrounding regions, 1960–1999: Relations to source area and climate. J. Geophys. Res.: Atmos., 106(D10), 10325–10333. https://doi.org/10.1029/2000JD900665

Sun, Y. B., and An, Z. S. (2005). Late Pliocene-Pleistocene changes in mass accumulation rates of eolian deposits on the central Chinese Loess Plateau. J. Geophys. Res.: Atmos., 110(D23), D23101. https://doi.org/10.1029/2005JD006064

Sun, Y. B., Chen, H. Y., Tada, R., Weiss, D., Lin, M., Toyoda, S., Yan, Y., and Isozaki, Y. (2013). ESR signal intensity and crystallinity of quartz from Gobi and sandy deserts in East Asia and implication for tracing Asian dust provenance. Geochem. Geophys. Geosyst., 14(8), 2615–2627. https://doi.org/10.1002/ggge.20162

Sun, Y. B., Clemens, S. C., An, Z. S., and Yu, Z. W. (2006). Astronomical timescale and palaeoclimatic implication of stacked 3.6-Myr monsoon records from the Chinese Loess Plateau. Quat. Sci. Rev., 25(1-2), 33–48. https://doi.org/10.1016/j.quascirev.2005.07.005

Sun, Y. B., and Liu, Q. S. (2007). Preliminary comparison of eolian depositions in the North Pacific and the Chinese Loess Plateau during the late Pliocence–early Pleistocene. Quat. Sci. (in Chinese), 27(2), 263–269. https://doi.org/10.3321/j.issn:1001-7410.2007.02.011

Tamburini, F., Adatte, T., Föllmi, K., Bernasconi, S. M., and Steinmann, P. (2003). Investigating the history of East Asian monsoon and climate during the last glacial–interglacial period (0–140 000 years): mineralogy and geochemistry of ODP Sites 1143 and 1144, South China Sea. Marine Geol., 201(1-3), 147–168. https://doi.org/10.1016/S0025-3227(03)00214-7

Tanaka, T. Y., and Chiba, M. (2006). A numerical study of the contributions of dust source regions to the global dust budget. Global Planet. Change, 52(1-4), 88–104. https://doi.org/10.1016/j.gloplacha.2006.02.002

Taylor, S. R., Mclennan, S. M., and McCulloch, M. T. (1983). Geochemistry of loess, continental crustal composition and crustal model ages. Geochim. Cosmochim. Acta, 47(11), 1897–1905. https://doi.org/10.1016/0016-7037(83)90206-5

Thompson, R., and Oldfield, F. (1986). Environmental Magnetism. London: Allen and Unwin.

Torrent, J., and Barrón, V. (2003). The visible diffuse reflectance spectrum in relation to the color and crystal properties of hematite. Clays Clay Miner., 51(3), 309–317. https://doi.org/10.1346/CCMN.2003.0510307

Torrent, J. and Barroón V. (2008). Diffuse reflectance spectroscopy. In A. L. Ulery and L. R. Drees (Eds.), Methods of Soil Analysis: Mineralogical Methods (pp. 367-387). Madison, WI, USA: Soil Science Society of America.

Torrent, J., Liu, Q. S., Bloemendal, J., and Barrón, V. (2007). Magnetic enhancement and iron oxides in the upper Luochuan loess–paleosol sequence, Chinese Loess Plateau. Soil Sci. Soc. Am. J., 71(5), 1570–1578. https://doi.org/10.2136/sssaj2006.0328

Wang, X. S., Yang, Z. Y., Chen, Y., Hu, J. Y., Tang, L., Sheng, M., and Løvlie, R. (2015). Deciphering magnetoclimatological patterns of late Early to early Middle Pleistocene loess–paleosol sequences in the western Chinese Loess Plateau. Global Planet. Change, 130, 37–46. https://doi.org/10.1016/j.gloplacha.2015.04.003

Wehausen, R., and Brumsack, H. J. (2002). Astronomical forcing of the East Asian monsoon mirrored by the composition of Pliocene South China Sea sediments. Earth Planet. Sci. Lett., 201(3-4), 621–636. https://doi.org/10.1016/S0012-821X(02)00746-X

Yang, S. L., Ding, F., and Ding, Z. L. (2006). Pleistocene chemical weathering history of Asian arid and semi-arid regions recorded in loess deposits of China and Tajikistan. Geochim. Cosmochim. Acta, 70(7), 1695–1709. https://doi.org/10.1016/j.gca.2005.12.012

Zhang, Q., Liu, Q. S., Li, J. H., and Sun, Y. B. (2018). An integrated study of the eolian dust in pelagic sediments from the North Pacific Ocean based on environmental magnetism, transmission electron microscopy, and diffuse reflectance spectroscopy. J. Geophys. Res.: Solid Earth, 123(5), 3358–3376. https://doi.org/10.1002/2017JB014951

Zhang, W. F., Chen, J., Ji, J. F., and Li, G. J. (2016). Evolving flux of Asian dust in the North Pacific Ocean since the late Oligocene. Aeolian Res., 23, 11–20. https://doi.org/10.1016/j.aeolia.2016.09.004

Zhang, Y. G., Ji, J. F., Balsam, W. L., Liu, L. W., and Chen, J. (2007). High resolution hematite and goethite records from ODP 1143, South China Sea: co-evolution of monsoonal precipitation and El Niño over the past 600,000 years. Earth and Planetary Science Letters, 264(1-2), 136–150. https://doi.org/10.1016/j.jpgl.2007.09.022

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Changes in diffuse reflectance spectroscopy properties of hematite in sediments from the North Pacific Ocean and implications for eolian dust evolution history

Qiang Zhang, QingSong Liu