O++ is an interesting species in the ionospheres of both the Earth and Venus. Recent measurements made by the Neutral Gas and Ion Mass Spectrometer (NGIMS) on board the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft provide the first firm detection of O++ in the Martian ionosphere. This study is devoted to an evaluation of the dominant O++ production and destruction channels in the dayside Martian ionosphere, by virtue of NGIMS data accumulated over a large number of MAVEN orbits. Our analysis reveals the dominant production channels to be double photoionization of O at low altitudes and photoionization of O+ at high altitudes, respectively, in response to the varying degree of O ionization. O++ destruction is shown to occur mainly via charge exchange with CO2 at low altitudes and with O at high altitudes. In the dayside median sense, an exact balance between O++ production and destruction is suggested by the data below 200 km. The apparent discrepancy from local photochemical equilibrium at higher altitudes is interpreted as a signature of strong O++ escape on Mars, characterized by an escape rate of 6×1022 s–1.
The photoelectron peak at 22–27 eV, a distinctive feature of the energetic electron distribution in the dayside Martian ionosphere, is a useful diagnostic of solar extreme ultraviolet (EUV) and X-ray ionization as well as of large-scale transport along magnetic field lines. In this work, we analyze the pitch angle distribution (PAD) of energetic electrons at 22–27 eV measured during several representative Mars Atmosphere and Volatile Evolution (MAVEN) orbits, based on the electron spectra gathered by MAVEN’s Solar Wind Electron Analyzer (SWEA) instrument. On the dayside, most photoelectron spectra show an isotropic PAD as is expected from production via solar EUV/X-ray ionization. The photoelectron spectra occasionally observed on the nightside show instead a strongly anisotropic PAD, indicative of cross-terminator transport along ambient magnetic field lines. This would in turn predict the presence of dayside photoelectrons, also with a strongly anisotropic PAD, which was indeed revealed in SWEA data. Comparison with magnetic field measurements made by the MAVEN Magnetometer suggests that on average the photoelectrons with anisotropic PAD stream away from Mars on the dayside and towards Mars on the nightside, further supporting the scenario of day-to-night transport. On both sides, anisotropic photoelectrons tend to be observed above the photoelectron exobase at ～160 km where photoelectron transport dominates over local production and energy degradation.