O++ is an interesting species in the ionospheres of both the Earth and Venus. Recent measurements made by the Neutral Gas and Ion Mass Spectrometer (NGIMS) on board the Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft provide the first firm detection of O++ in the Martian ionosphere. This study is devoted to an evaluation of the dominant O++ production and destruction channels in the dayside Martian ionosphere, by virtue of NGIMS data accumulated over a large number of MAVEN orbits. Our analysis reveals the dominant production channels to be double photoionization of O at low altitudes and photoionization of O+ at high altitudes, respectively, in response to the varying degree of O ionization. O++ destruction is shown to occur mainly via charge exchange with CO2 at low altitudes and with O at high altitudes. In the dayside median sense, an exact balance between O++ production and destruction is suggested by the data below 200 km. The apparent discrepancy from local photochemical equilibrium at higher altitudes is interpreted as a signature of strong O++ escape on Mars, characterized by an escape rate of 6×1022 s–1.
Photoelectrons are produced by solar Extreme Ultraviolet radiation and contribute significantly to the local ionization and heat balances in planetary upper atmospheres. When the effect of transport is negligible, the photoelectron energy distribution is controlled by a balance between local production and loss, a condition usually referred to as local energy degradation. In this study, we examine such a condition for photoelectrons near Mars, with the aid of a multi-instrument Mars Atmosphere and Volatile Evolution data set gathered over the inbound portions of a representative dayside MAVEN orbit. Various photoelectron production and loss processes considered here include primary and secondary ionization, inelastic collisions with atmospheric neutrals associated with both excitation and ionization, as well as Coulomb collisions with ionospheric thermal electrons. Our calculations indicate that photoelectron production occurs mainly via primary ionization and degradation from higher energy states during inelastic collisions; photoelectron loss appears to occur almost exclusively via degradation towards lower energy states via inelastic collisions above 10 eV, but the effect of Coulomb collisions becomes important at lower energies. Over the energy range of 30–55 eV (chosen to reduce the influence of the uncertainty in spacecraft charging), we find that the condition of local energy degradation is very well satisfied for dayside photoelectrons from 160 to 250 km. No evidence of photoelectron transport is present over this energy range.